{"id":97810,"date":"2025-03-18T07:29:25","date_gmt":"2025-03-18T07:29:25","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/oximy\/"},"modified":"2026-07-22T14:14:47","modified_gmt":"2026-07-22T14:14:47","slug":"oximy","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/cs\/fact\/oximy\/","title":{"rendered":"Oximy"},"content":{"rendered":"

Odhaduje se, \u017ee a\u017e 700 000 pracovn\u00edk\u016f v EU je vystaveno p\u016fsoben\u00ed oxim\u016f. Oximy se pou\u017e\u00edvaj\u00ed v tekut\u00fdch barv\u00e1ch a n\u00e1t\u011brov\u00fdch hmot\u00e1ch (kde p\u016fsob\u00ed jako l\u00e1tky zabra\u0148uj\u00edc\u00ed tvorb\u011b krusty) a v n\u011bkter\u00fdch typech tmel\u016f na b\u00e1zi silanu. Vzhledem k jejich t\u011bkavosti je hlavn\u00ed cestou expozice vdechov\u00e1n\u00ed. <\/p><\/blockquote>\n

Oximy p\u0159edstavuj\u00ed skupinu l\u00e1tek. Oximy, jako je methylethylketoxim neboli 2-butanon-oxim (MEKO) a aceton-oxim, pou\u017e\u00edvan\u00e9 v barv\u00e1ch, lac\u00edch a tmel\u00edch, jsou podle CLP na\u0159\u00edzen\u00ed o klasifikaci ozna\u010dov\u00e1n\u00ed a balen\u00ed l\u00e1tek a sm\u011bs\u00ed za\u0159azeny do kategorie karcinogen\u016f 1B. MEKO je d\u00e1le klasifikov\u00e1no jako l\u00e1tka s toxicitou pro specifick\u00e9 c\u00edlov\u00e9 org\u00e1ny s \u00fa\u010dinky na horn\u00ed d\u00fdchac\u00ed cesty (STOT SE 1, H370) a krevn\u00ed syst\u00e9m (STOT RE 2, H373) p\u0159i dlouhodob\u00e9 nebo opakovan\u00e9 expozici. Podobn\u00e9 \u00fa\u010dinky na krevn\u00ed syst\u00e9m byly pozorov\u00e1ny u aceton-oximu a dal\u0161\u00edch oxim\u016f. <\/p>\n

Kde se vyskytuj\u00ed rizika<\/h2>\n

K expozici p\u0159i pr\u00e1ci doch\u00e1z\u00ed hlavn\u011b ve f\u00e1zi nan\u00e1\u0161en\u00ed tekut\u00fdch barev a n\u00e1t\u011br\u016f, kdy se rozpou\u0161t\u011bdla odpa\u0159uj\u00ed. Aplikace barev a n\u00e1t\u011br\u016f obvykle prob\u00edh\u00e1 v zorn\u00e9m poli pracovn\u00edka, kter\u00e9 je v d\u00fdchac\u00ed z\u00f3n\u011b, tak\u017ee expozice v\u00fdpar\u016fm je vysok\u00e1. V p\u0159\u00edpad\u011b silan\u016f uvol\u0148uj\u00edc\u00edch oximy se oxymy uvol\u0148uj\u00ed pr\u016fb\u011b\u017en\u011b b\u011bhem f\u00e1ze vytvrzov\u00e1n\u00ed, dokud tmely zcela nevytvrdnou. Vysokou expozici lze o\u010dek\u00e1vat v odv\u011btv\u00ed mal\u00ed\u0159stv\u00ed a lak\u00fdrnictv\u00ed a p\u0159i st\u0159\u00edk\u00e1n\u00ed a lakov\u00e1n\u00ed motorov\u00fdch vozidel. V d\u016fsledku toho jsou profesemi s vysok\u00fdm rizikem expozice oxym\u016fm mal\u00ed\u0159i, lak\u00fdrn\u00edci motorov\u00fdch vozidel (p\u0159i lakov\u00e1n\u00ed), ale tak\u00e9 instalat\u00e9\u0159i a mont\u00e9\u0159i p\u0159i pou\u017e\u00edv\u00e1n\u00ed tmel\u016f uvol\u0148uj\u00edc\u00edch oxymy. Krom\u011b toho mohou b\u00fdt ohro\u017eeny i dal\u0161\u00ed profese, kter\u00e9 vstupuj\u00ed do pracovn\u00edch prostor, v nich\u017e byly d\u0159\u00edve pou\u017eity v\u00fdrobky obsahuj\u00edc\u00ed oximy a kter\u00e9 se st\u00e1le odpa\u0159uj\u00ed. <\/p>\n

V\u00edce o l\u00e1tce<\/h2>\n

Oximy jsou bezbarv\u00e9, t\u011bkav\u00e9 kapaliny s aromatick\u00fdm z\u00e1pachem. Mezi nej\u010dast\u011bji pou\u017e\u00edvan\u00e9 oximy pat\u0159\u00ed 2-butanon-oxim (MEKO), aceton-oxim, 2-pentanon-oxim (MPKO) a 4-methylpentanon-oxim (MIBKO). T\u00e9m\u011b\u0159 nikdy se v\u0161ak nepou\u017e\u00edvaj\u00ed v \u010dist\u00e9 form\u011b, ale v n\u00edzk\u00fdch koncentrac\u00edch (obvykle < 1 %) jako prost\u0159edky proti tvorb\u011b krusty v (p\u0159ev\u00e1\u017en\u011b alkylov\u00fdch) barv\u00e1ch a n\u00e1t\u011brov\u00fdch hmot\u00e1ch, p\u0159\u00edpadn\u011b ve v\u00e1zan\u00e9 form\u011b v silanov\u00fdch tmel\u00edch uvol\u0148uj\u00edc\u00edch oximy. <\/p>\n

Nebezpe\u010d\u00ed, kter\u00e1 mohou nastat<\/h2>\n

Dosud nejsou k dispozici \u017e\u00e1dn\u00e9 epidemiologick\u00e9 \u00fadaje o toxikologick\u00fdch \u00fa\u010dinc\u00edch jak\u00fdchkoli oxim\u016f na \u010dlov\u011bka. Ve studi\u00edch na zv\u00ed\u0159atech jsou po or\u00e1ln\u00ed nebo inhala\u010dn\u00ed expozici oxim\u016fm hlavn\u00edmi c\u00edlov\u00fdmi org\u00e1ny j\u00e1tra, slezina a krevn\u00ed syst\u00e9m. Krom\u011b toho byly u MEKO pozorov\u00e1ny p\u0159echodn\u00e9 narkotick\u00e9 \u00fa\u010dinky a podr\u00e1\u017ed\u011bn\u00ed k\u016f\u017ee. Je t\u0159eba poznamenat, \u017ee po derm\u00e1ln\u00ed expozici MEKO jsou mo\u017en\u00e9 alergick\u00e9 ko\u017en\u00ed reakce. K dne\u0161n\u00edmu dni jsou pouze MEKO a aceton-oxim harmonizov\u00e1ny jako Carc. 1B (p\u0159edpokl\u00e1dan\u00e1 karcinogenita pro \u010dlov\u011bka). Pro MPKO, MIBKO a cyklohexanon-oxim, kter\u00e9 se pou\u017e\u00edvaj\u00ed jako alternativn\u00ed oximy pro MEKO a aceton-oxim, nejsou doposud k dispozici odpov\u00eddaj\u00edc\u00ed \u00fadaje, kter\u00e9 by od\u016fvod\u0148ovaly klasifikaci CLH jako karcinogenn\u00ed. Po inhalaci MEKO se u zv\u00ed\u0159at vyvinula rakovina jater a enzymatickou cestu lze p\u0159edpokl\u00e1dat i u lid\u00ed. <\/p>\n

V sou\u010dasn\u00e9 dob\u011b chyb\u00ed d\u016fkazy o rakovin\u011b jater u lid\u00ed na z\u00e1klad\u011b expozice MEKO a o mo\u017en\u00e9 dob\u011b latence.<\/strong><\/p>\n

Co m\u016f\u017eete ud\u011blat<\/h2>\n

Nej\u00fa\u010dinn\u011bj\u0161\u00edm zp\u016fsobem, jak zabr\u00e1nit expozici a mo\u017en\u00e9 rakovin\u011b jater, je nahrazen\u00ed bezpe\u010dn\u011bj\u0161\u00edmi alternativami bez obsahu Oxim\u016f. V p\u0159\u00edpad\u011b oxid\u016f v barv\u00e1ch a lac\u00edch mohou b\u00fdt alternativn\u00ed n\u00e1t\u011brov\u00e9 syst\u00e9my, nap\u0159\u00edklad barvy na vodn\u00ed b\u00e1zi a akrylov\u00e9 nebo polyuretanov\u00e9 (PU) syst\u00e9my. Na trhu jsou k dispozici alternativn\u00ed prost\u0159edky proti okusu pro barvy na b\u00e1zi rozpou\u0161t\u011bdel, kter\u00e9 obsahuj\u00ed aminoslou\u010deniny. Pro silikonov\u00e9 tmely jsou k dispozici alternativy bez obsahu oxid\u016f v podob\u011b acetoxidov\u00fdch, benzamidov\u00fdch, aminov\u00fdch, alkoxidov\u00fdch a lakt\u00e1tov\u00fdch esterov\u00fdch syst\u00e9m\u016f. Pou\u017eiteln\u00e9 jsou tak\u00e9 silikonov\u00e9 tmely na alternativn\u00ed b\u00e1zi (nap\u0159. polyuretan nebo polymer zakon\u010den\u00fd silanem (STP)). Tam, kde nen\u00ed mo\u017en\u00e1 n\u00e1hrada oxim\u016f a pou\u017eit\u00ed oxim\u016f se nelze vyhnout, je t\u0159eba p\u0159ijmout opat\u0159en\u00ed ke sn\u00ed\u017een\u00ed expozice. Nej\u00fa\u010dinn\u011bj\u0161\u00edm zp\u016fsobem, jak zabr\u00e1nit expozici, je vyvinout a pou\u017e\u00edvat uzav\u0159en\u00e9 syst\u00e9my. Pokud to nen\u00ed mo\u017en\u00e9, m\u011bla by b\u00fdt zavedena technick\u00e1 opat\u0159en\u00ed, jako je \u00fa\u010dinn\u00e9 m\u00edstn\u00ed ods\u00e1v\u00e1n\u00ed nebo dobr\u00e9 v\u011btr\u00e1n\u00ed pracovi\u0161t\u011b, a tak\u00e9 kontrola jejich \u00fa\u010dinnosti, aby se zajistilo, \u017ee expozice par\u00e1m s Oximy z barev nebo tmel\u016f bude co nejv\u00edce technicky omezena.
\nProv\u00e1d\u011bjte pravideln\u00e9 hodnocen\u00ed expozice, abyste zkontrolovali, zda jsou va\u0161e zaveden\u00e1 ochrann\u00e1 opat\u0159en\u00ed \u00fa\u010dinn\u00e1 nebo zda je t\u0159eba p\u0159ijmout dal\u0161\u00ed opat\u0159en\u00ed. Pracovn\u00edci si mus\u00ed b\u00fdt v\u011bdomi mo\u017en\u00fdch \u00fa\u010dink\u016f expozice a m\u011bli by b\u00fdt pravideln\u011b \u0161koleni o kontroln\u00edch opat\u0159en\u00edch nezbytn\u00fdch pro bezpe\u010dnou pr\u00e1ci s oximy, aby se zabr\u00e1nilo expozici. M\u011bli by b\u00fdt vyzv\u00e1ni, aby hl\u00e1sili prvn\u00ed p\u0159\u00edznaky, jako jsou z\u00e1vrat\u011b, podr\u00e1\u017ed\u011bn\u00ed k\u016f\u017ee a ko\u017en\u00ed alergie. Doporu\u010duje se zapojen\u00ed pracovn\u00edho l\u00e9ka\u0159e. Krom\u011b toho pro\u0161kolte pracovn\u00edky o \u00fa\u010dinn\u00fdch hygienick\u00fdch opat\u0159en\u00edch. <\/p>\n

Zajist\u011bte, aby pracovn\u00edci m\u011bli odpov\u00eddaj\u00edc\u00ed prost\u0159edky osobn\u00ed ochrany, jako je ochrann\u00fd od\u011bv a rukavice, je-li to nutn\u00e9. Osobn\u00ed ochrana (OOPP) by m\u011bla b\u00fdt pou\u017e\u00edv\u00e1na pouze jako posledn\u00ed mo\u017enost a m\u011bla by b\u00fdt zva\u017eov\u00e1na pouze do\u010dasn\u011b, po vy\u010derp\u00e1n\u00ed mo\u017en\u00fdch technick\u00fdch \u0159e\u0161en\u00ed. Pokud se pou\u017e\u00edvaj\u00ed osobn\u00ed ochrann\u00e9 pracovn\u00ed prost\u0159edky pro opakovan\u00e9 pou\u017eit\u00ed, dbejte na to, aby byly odstran\u011bny p\u0159edpokl\u00e1dan\u00fdm zp\u016fsobem (respira\u010dn\u00ed za\u0159\u00edzen\u00ed v posledn\u00ed \u0159ad\u011b), pravideln\u011b \u010di\u0161t\u011bny a skladov\u00e1ny tak, aby se zabr\u00e1nilo jejich kontaminaci. <\/p>\n

Odkazy: BAuA, CLP na\u0159\u00edzen\u00ed o klasifikaci ozna\u010dov\u00e1n\u00ed a balen\u00ed l\u00e1tek a sm\u011bs\u00ed, BG BAU<\/em><\/p>\n","protected":false},"template":"","carcinogens":[8132],"class_list":["post-97810","fact","type-fact","status-publish","hentry","carcinogens-oximy"],"yoast_head":"\nOximy - STOP carcinogens at work<\/title>\n<meta name=\"description\" content=\"Odhaduje se, \u017ee a\u017e 700 000 pracovn\u00edk\u016f v EU je vystaveno p\u016fsoben\u00ed oxim\u016f. 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