{"id":98101,"date":"2024-01-04T09:27:34","date_gmt":"2024-01-04T09:27:34","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/nitrosaminy\/"},"modified":"2026-10-22T11:33:53","modified_gmt":"2026-10-22T11:33:53","slug":"nitrosaminy","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/cs\/fact\/nitrosaminy\/","title":{"rendered":"Nitrosaminy"},"content":{"rendered":"<blockquote><p>Jen v gum\u00e1rensk\u00e9m pr\u016fmyslu je v EU zam\u011bstn\u00e1no v\u00edce ne\u017e 350&nbsp;000 pracovn\u00edk\u016f; nav\u00edc se odhaduje, \u017ee p\u0159ibli\u017en\u011b 260&nbsp;000 pracovn\u00edk\u016f je vystaveno p\u016fsoben\u00ed kapalin pro obr\u00e1b\u011bn\u00ed kov\u016f a inhibitor\u016f koroze. N-nitrosaminy se obvykle nevyr\u00e1b\u011bj\u00ed z\u00e1m\u011brn\u011b, ale obvykle vznikaj\u00ed ze sekund\u00e1rn\u00edch amin\u016f a nitroza\u010dn\u00edch \u010dinidel za ur\u010dit\u00fdch reak\u010dn\u00edch podm\u00ednek. Typick\u00e1 pracovi\u0161t\u011b, kde se N-nitrosaminy mohou vyskytovat, jsou gum\u00e1rensk\u00fd, ko\u017eed\u011bln\u00fd, kovoobr\u00e1b\u011bc\u00ed a chemick\u00fd pr\u016fmysl. Inhalace a derm\u00e1ln\u00ed expozice jsou hlavn\u00edmi cestami expozice nitrosamin\u016fm. Mnoho N-nitrosamin\u016f je podle CLP na\u0159\u00edzen\u00ed o klasifikaci ozna\u010dov\u00e1n\u00ed a balen\u00ed l\u00e1tek a sm\u011bs\u00ed klasifikov\u00e1no jako karcinogen kategorie 1A, 1B nebo 2. Epidemiologick\u00e9 \u00fadaje nazna\u010duj\u00ed, \u017ee expozice nitrosamin\u016fm v pracovn\u00edm prost\u0159ed\u00ed i v b\u011b\u017en\u00e9 populaci m\u016f\u017ee b\u00fdt spojena s rizikem vzniku r\u016fzn\u00fdch typ\u016f rakoviny.     <\/p><\/blockquote>\n<h2>Kde se vyskytuj\u00ed rizika<\/h2>\n<p>K expozici Nitrosamin\u016fm m\u016f\u017ee doch\u00e1zet v gum\u00e1rensk\u00e9m pr\u016fmyslu p\u0159i \u010dinnostech, jako je v\u00e1\u017een\u00ed, m\u00edch\u00e1n\u00ed, zpracov\u00e1n\u00ed polotovar\u016f, vulkanizace a n\u00e1sledn\u00e1 \u00faprava. Potenci\u00e1ln\u00edmi zdroji Nitrosamin\u016f mohou b\u00fdt tak\u00e9 gum\u00e1rensk\u00e9 v\u00fdrobky. Expozice byla hl\u00e1\u0161ena v kovozpracuj\u00edc\u00edm pr\u016fmyslu, pokud kapaliny pro zpracov\u00e1n\u00ed kov\u016f obsahuj\u00ed vysok\u00e9 hladiny dusi\u010dnan\u016f\/nitrit\u016f. Typick\u00fdmi \u00fakoly jsou \u00fadr\u017eba a servis stroj\u016f, ru\u010dn\u00ed manipulace s obr\u00e1b\u011bc\u00edmi stroji za t\u011bsn\u00e9 p\u0159\u00edtomnosti obsluhy a pravd\u011bpodobnost rozst\u0159iku, rozst\u0159iku nebo odpa\u0159ov\u00e1n\u00ed kapalin a sm\u011bs\u00ed pro obr\u00e1b\u011bn\u00ed kov\u016f b\u011bhem provozu. Nen\u00ed v\u0161ak zn\u00e1mo, zda tyto podm\u00ednky ji\u017e plat\u00ed v Evrop\u011b. V\u00fdroba a pou\u017e\u00edv\u00e1n\u00ed amin\u016f v chemick\u00e9m pr\u016fmyslu, jako\u017e i dekantace a pln\u011bn\u00ed amin\u016f a jejich pou\u017e\u00edv\u00e1n\u00ed v dal\u0161\u00edch chemick\u00fdch procesech, nap\u0159. p\u0159i v\u00fdrob\u011b n\u00e1t\u011br\u016f koagulac\u00ed, p\u0159i v\u00fdrob\u011b polyakrylonitrilov\u00fdch vl\u00e1ken, jsou pracovi\u0161t\u011b, kde se mohou vyskytovat Nitrosaminy. V minulosti bylo mo\u017en\u00e9 nal\u00e9zt dal\u0161\u00ed posti\u017een\u00e1 pracovi\u0161t\u011b tak\u00e9 v ko\u017eed\u011bln\u00e9m pr\u016fmyslu, v elektronick\u00e9m pr\u016fmyslu a ve sl\u00e9v\u00e1rn\u00e1ch.      <\/p>\n<h2>V\u00edce o l\u00e1tce<\/h2>\n<p>Nitrosaminy se nevyr\u00e1b\u011bj\u00ed ani nepou\u017e\u00edvaj\u00ed. Nitrosaminy obvykle vznikaj\u00ed ze sekund\u00e1rn\u00edch amin\u016f p\u0159i kontaktu s jin\u00fdmi dus\u00edkat\u00fdmi slou\u010deninami a nitroza\u010dn\u00edmi \u010dinidly. Nitroza\u010dn\u00edmi \u010dinidly jsou kyselina dusi\u010dn\u00e1 a jej\u00ed soli, dusitany, oxidy dus\u00edku z v\u00fdfukov\u00fdch plyn\u016f motor\u016f nebo organick\u00e9 nitroslou\u010deniny a nitrososlou\u010deniny. Sekund\u00e1rn\u00ed aminy mohou b\u00fdt p\u0159\u00edtomny v chemick\u00fdch p\u0159\u00edsad\u00e1ch nebo jako slo\u017eky z hotov\u00fdch v\u00fdrobk\u016f. Zn\u00e1m\u00e9 sekund\u00e1rn\u00ed aminy s potenci\u00e1lem vytv\u00e1\u0159et Nitrosaminy jsou nap\u0159. diethylamin, diethanolamin, diethylpropylamin, morfolin, pyrrolidin. Sekund\u00e1rn\u00ed aminy mohou v p\u0159\u00edslu\u0161n\u00fdch mno\u017estv\u00edch vznikat tak\u00e9 z jin\u00fdch slou\u010denin obsahuj\u00edc\u00edch dus\u00edk, nap\u0159. hydrol\u00fdzou, termick\u00fdm nebo biogenn\u00edm rozkladem. Typick\u00e9 sekund\u00e1rn\u00ed aminy lze nal\u00e9zt tak\u00e9 mezi inhibitory koroze, urychlova\u010di vulkanizace, rozpou\u0161t\u011bdly a vodou m\u00edsiteln\u00fdmi nebo vodou m\u00edsen\u00fdmi chladic\u00edmi mazivy, jako jsou kapaliny pro obr\u00e1b\u011bn\u00ed kov\u016f.          <\/p>\n<h2>Nebezpe\u010d\u00ed, kter\u00e1 mohou nastat<\/h2>\n<p>Vystaven\u00ed Nitrosamin\u016fm je spojov\u00e1no s celou \u0159adou typ\u016f rakoviny, nap\u0159. se vznikem rakoviny mo\u010dov\u00e9ho m\u011bch\u00fd\u0159e, \u017ealudku, j\u00edcnu, prostaty, slinivky b\u0159i\u0161n\u00ed a jater, leuk\u00e9mie a mnoho\u010detn\u00e9ho myelomu.<\/p>\n<p><strong>Doba latence mezi expozic\u00ed a vznikem rakoviny se odhaduje na 15 let.<\/strong><\/p>\n<h2>Co m\u016f\u017eete ud\u011blat<\/h2>\n<p>V prvn\u00ed linii jsou opat\u0159en\u00edmi eliminace a prevence rizik. Nahra\u010fte sekund\u00e1rn\u00ed aminy vhodn\u00fdmi n\u00e1hradami pro konkr\u00e9tn\u00ed aplikaci, nap\u0159. prim\u00e1rn\u00edmi nebo terci\u00e1rn\u00edmi aminy a alkanolaminy. Je zn\u00e1mo n\u011bkolik sekund\u00e1rn\u00edch amin\u016f, kter\u00e9 netvo\u0159\u00ed karcinogenn\u00ed N-nitrosaminy, nap\u0159. dicyklohexylamin. Pro pou\u017eit\u00ed sekund\u00e1rn\u00edch amin\u016f, nap\u0159. v gum\u00e1rensk\u00e9m pr\u016fmyslu, jsou k dispozici r\u016fzn\u00e9 alternativn\u00ed chemick\u00e9 syst\u00e9my. Chcete-li sn\u00ed\u017eit riziko tvorby N-nitrosamin\u016f, udr\u017eujte nitroza\u010dn\u00ed \u010dinidla nebo prekurzory, jako jsou dusitany, mimo dosah a udr\u017eujte n\u00edzkou koncentraci sekund\u00e1rn\u00edch amin\u016f. V p\u0159\u00edpad\u011b pot\u0159eby aplikujte inhibitory tvorby N-nitrosamin\u016f, jako jsou kyselina askorbov\u00e1, sulfam\u00e1ty, kyselina p-aminobenzoov\u00e1, alfa-tokoferol, prim\u00e1rn\u00ed aminy a prim\u00e1rn\u00ed alkanolaminy. Prov\u011b\u0159te nebo sledujte maxim\u00e1ln\u00ed koncentraci sekund\u00e1rn\u00edch amin\u016f, nitroza\u010dn\u00edch \u010dinidel nebo hodnotu pH ve v\u00fdrobc\u00edch. Dodr\u017eujte n\u00e1rodn\u00ed omezen\u00ed pou\u017eit\u00ed, pokud existuj\u00ed. Nen\u00ed-li n\u00e1hrada mo\u017en\u00e1, m\u011bla by se zav\u00e9st pravideln\u00e1 hodnocen\u00ed expozice za \u00fa\u010delem kontroly \u00fa\u010dinnosti ochrann\u00fdch opat\u0159en\u00ed nebo pot\u0159eby dal\u0161\u00edch krok\u016f. Technick\u00e1 ochrann\u00e1 opat\u0159en\u00ed, jako jsou uzav\u0159en\u00e9 syst\u00e9my nebo ods\u00e1v\u00e1n\u00ed N-nitrosamin\u016f vznikaj\u00edc\u00edch v procesu, jsou alternativou, pokud nelze prov\u00e9st substituci. Pr\u016fb\u011b\u017en\u011b informujte pracovn\u00edky o \u00fa\u010dinc\u00edch expozice. Krom\u011b toho pro\u0161kolte pracovn\u00edky o rizic\u00edch, bezpe\u010dn\u00fdch pracovn\u00edch postupech a \u00fa\u010dinn\u00fdch hygienick\u00fdch opat\u0159en\u00edch. Zajist\u011bte, aby pracovn\u00edci m\u011bli v p\u0159\u00edpad\u011b pot\u0159eby odpov\u00eddaj\u00edc\u00ed prost\u0159edky osobn\u00ed ochrany, jako je ochrann\u00fd od\u011bv a rukavice. Osobn\u00ed ochrana by m\u011bla b\u00fdt pou\u017eita a\u017e jako posledn\u00ed mo\u017enost, po vy\u010derp\u00e1n\u00ed dostupn\u00fdch technick\u00fdch \u0159e\u0161en\u00ed.             <\/p>\n<p><em>Odkazy: AGS, ECHA, FIOH, DGUV, HSE, BAuA, Statista<\/em><\/p>\n","protected":false},"template":"","carcinogens":[8122],"class_list":["post-98101","fact","type-fact","status-publish","hentry","carcinogens-nitrosaminy"],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v28.8 (Yoast SEO v28.8) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>Nitrosaminy - STOP karcinogen\u016fm p\u0159i pr\u00e1ci<\/title>\n<meta name=\"description\" content=\"Podez\u0159en\u00ed na karcinogenitu, proto\u017ee po\u0161kozuje genetick\u00fd materi\u00e1l, zp\u016fsobuje rakovinu \u017ealudku nebo vede k alergick\u00e9 kontaktn\u00ed dermatitid\u011b.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/stopcarcinogensatwork.eu\/cs\/fact\/nitrosaminy\/\" \/>\n<meta property=\"og:locale\" content=\"cs_CZ\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Nitrosaminy\" \/>\n<meta property=\"og:description\" content=\"Podez\u0159en\u00ed na karcinogenitu, proto\u017ee po\u0161kozuje genetick\u00fd materi\u00e1l, zp\u016fsobuje rakovinu \u017ealudku nebo vede k alergick\u00e9 kontaktn\u00ed dermatitid\u011b.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/stopcarcinogensatwork.eu\/cs\/fact\/nitrosaminy\/\" \/>\n<meta property=\"og:site_name\" content=\"STOP karcinogen\u016fm p\u0159i pr\u00e1ci\" \/>\n<meta property=\"article:modified_time\" content=\"2026-10-22T11:33:53+00:00\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Odhadovan\u00e1 doba \u010dten\u00ed \" \/>\n\t<meta name=\"twitter:data1\" content=\"3 minuty\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/stopcarcinogensatwork.eu\\\/cs\\\/fact\\\/nitrosaminy\\\/\",\"url\":\"https:\\\/\\\/stopcarcinogensatwork.eu\\\/cs\\\/fact\\\/nitrosaminy\\\/\",\"name\":\"Nitrosaminy - 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