{"id":94744,"date":"2023-08-29T10:09:24","date_gmt":"2023-08-29T10:09:24","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/epichlorohydrin\/"},"modified":"2026-06-13T11:31:47","modified_gmt":"2026-06-13T11:31:47","slug":"epichlorohydrin","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/sk\/fact\/epichlorohydrin\/","title":{"rendered":"Epichl\u00f3rhydr\u00edn"},"content":{"rendered":"

Posledn\u00fd odhadovan\u00fd po\u010det pracovn\u00edkov vystaven\u00fdch v E\u00da p\u00f4sobeniu Epichl\u00f3rhydr\u00ednu (1-chl\u00f3r-2,3-epoxyprop\u00e1nu) z roku 2011 je pribli\u017ene 44 000. Za hlavn\u00fd sp\u00f4sob expoz\u00edcie sa pova\u017euje inhal\u00e1cia, ale pracovn\u00edci m\u00f4\u017eu by\u0165 vystaven\u00ed aj ko\u017en\u00e9mu kontaktu. Epichl\u00f3rhydr\u00edn je klasifikovan\u00fd ako karcinog\u00e9nna kateg\u00f3ria 1B (pod\u013ea nariadenia CLP (Klasifik\u00e1cia, ozna\u010dovanie a balenie)), \u010do znamen\u00e1, \u017ee sa na z\u00e1klade d\u00f4kazov v testoch na zvierat\u00e1ch predpoklad\u00e1 jeho karcinog\u00e9nny potenci\u00e1l pre \u013eud\u00ed. Expoz\u00edcia Epichl\u00f3rhydr\u00ednom sa sp\u00e1ja s v\u00fdskytom rakoviny p\u013e\u00fac a n\u00e1dorov centr\u00e1lneho nervov\u00e9ho syst\u00e9mu. <\/p><\/blockquote>\n

Kde sa vyskytuj\u00fa rizik\u00e1<\/h2>\n

K profesion\u00e1lnej expoz\u00edcii Epichl\u00f3rhydr\u00ednu m\u00f4\u017ee d\u00f4js\u0165 pri jeho v\u00fdrobe z chl\u00f3ru, ako aj pri v\u00fdrobe epoxidov\u00fdch \u017eiv\u00edc pou\u017e\u00edvan\u00fdch v n\u00e1teroch, lepidl\u00e1ch a plastoch. Epoxidov\u00e9 \u017eivice maj\u00fa r\u00f4zne aplik\u00e1cie v priemyseln\u00fdch odvetviach, ako s\u00fa farby, lepidl\u00e1, automobilov\u00fd a leteck\u00fd priemysel, Stavebn\u00edctvo, zariadenia na v\u00fdrobu energie z obnovite\u013en\u00fdch zdrojov a elektronika (pou\u017e\u00edvaj\u00fa sa na dosky s plo\u0161n\u00fdmi spojmi a na zapuzdrenie elektronick\u00fdch s\u00fa\u010diastok s cie\u013eom chr\u00e1ni\u0165 ich pred po\u0161koden\u00edm). Epichl\u00f3rhydr\u00edn sa \u010falej pou\u017e\u00edva v \u0161peci\u00e1lnych \u017eiviciach a polym\u00e9roch na \u00fapravu vody, \u017eiviciach s vysokou pevnos\u0165ou za mokra pre papierensk\u00fd priemysel alebo prostredn\u00edctvom i\u00f3novej v\u00fdmeny na \u010distenie vzduchu a vody. Okrem toho sa pou\u017e\u00edva ako rozp\u00fa\u0161\u0165adlo pre estery a \u00e9tery celul\u00f3zy, pri spracovan\u00ed vlny a bavlny a v gum\u00e1rensk\u00fdch procesoch. Okrem toho medzi rizikov\u00e9 povolania z h\u013eadiska expoz\u00edcie patria pracovn\u00edci v z\u00e1vodoch na chemick\u00fa synt\u00e9zu polyolov na v\u00fdrobu tuh\u00fdch polyuret\u00e1nov\u00fdch pien a povrchovo akt\u00edvnych l\u00e1tok na pranie v\u00fdrobkov. <\/p>\n

Viac o l\u00e1tke<\/h2>\n

Epichl\u00f3rhydr\u00edn je bezfarebn\u00e1 hor\u013eav\u00e1 kvapalina so \u0161tip\u013eav\u00fdm cesnakov\u00fdm z\u00e1pachom, stredne rozpustn\u00e1 vo vode, ale mie\u0161ate\u013en\u00e1 s v\u00e4\u010d\u0161inou pol\u00e1rnych organick\u00fdch rozp\u00fa\u0161\u0165adiel. Pri horen\u00ed vytv\u00e1ra toxick\u00e9 a koroz\u00edvne v\u00fdpary chlorovod\u00edka a chl\u00f3ru. Epichl\u00f3rhydr\u00edn prudko reaguje s hlin\u00edkom, zinkom, alkoholmi, fenolmi, am\u00ednmi a organick\u00fdmi kyselinami; vznik\u00e1 nebezpe\u010denstvo po\u017eiaru a v\u00fdbuchu. <\/p>\n

V platnosti je z\u00e1v\u00e4zn\u00e1 limitn\u00e1 hodnota expoz\u00edcie na pracovisku v r\u00e1mci E\u00da vo v\u00fd\u0161ke 1,9 mg\/m\u00b3 (TWA – \u010casovo v\u00e1\u017een\u00fd priemer).<\/p>\n

Nebezpe\u010denstv\u00e1, ktor\u00e9 sa m\u00f4\u017eu vyskytn\u00fa\u0165<\/h2>\n

Za prim\u00e1rnu cestu expoz\u00edcie sa pova\u017euje vdychovanie p\u00e1r Epichl\u00f3rhydr\u00ednu, ale je mo\u017en\u00fd aj v\u00fdznamn\u00fd pr\u00edjem cez poko\u017eku. Kr\u00e1tkodob\u00e9 vystavenie epichl\u00f3rhydr\u00ednu m\u00f4\u017ee sp\u00f4sobi\u0165 podr\u00e1\u017edenie o\u010d\u00ed, d\u00fdchac\u00edch ciest a poko\u017eky. Vdychovanie p\u00e1r m\u00f4\u017ee sp\u00f4sobi\u0165 reakcie podobn\u00e9 astme. Okrem toho kontakt s Epichl\u00f3rhydr\u00ednom m\u00f4\u017ee podr\u00e1\u017edi\u0165 a pop\u00e1li\u0165 poko\u017eku a o\u010di. Pri vysok\u00fdch \u00farovniach expoz\u00edcie sa m\u00f4\u017ee vyskytn\u00fa\u0165 nevo\u013enos\u0165, vracanie, ka\u0161e\u013e, d\u00fdchavi\u010dnos\u0165, z\u00e1pal p\u013e\u00fac, p\u013e\u00facny ed\u00e9m, \u00fa\u010dinky na centr\u00e1lny nervov\u00fd syst\u00e9m a po\u0161kodenie obli\u010diek a pe\u010dene. Opakovan\u00fd alebo dlhodob\u00fd kontakt s Epichl\u00f3rhydr\u00ednom m\u00f4\u017ee sp\u00f4sobi\u0165 senzibiliz\u00e1ciu ko\u017ee. Okrem toho chronick\u00e1 expoz\u00edcia Epichl\u00f3rhydr\u00ednu m\u00f4\u017ee ma\u0165 \u00fa\u010dinky na obli\u010dky, pe\u010de\u0148 a p\u013e\u00faca, ako aj zv\u00fd\u0161en\u00e9 riziko rakoviny lymfatick\u00fdch a krvotvorn\u00fdch org\u00e1nov. <\/p>\n

\u010co m\u00f4\u017eete urobi\u0165<\/h2>\n

Naj\u00fa\u010dinnej\u0161\u00edm sp\u00f4sobom prevencie expoz\u00edcie je n\u00e1hrada epichl\u00f3rhydr\u00ednu, napr\u00edklad alternat\u00edvnymi met\u00f3dami v\u00fdroby epoxidov\u00fdch \u017eiv\u00edc; n\u00e1hradami epoxidov\u00fdch \u017eiv\u00edc v r\u00f4znych aplik\u00e1ci\u00e1ch, ako s\u00fa n\u00e1tery, Stavebn\u00edctvo, lepidl\u00e1, lamin\u00e1ty a kompozity; alternat\u00edvnymi postupmi synt\u00e9zy glycer\u00ednu a n\u00e1hradami epichl\u00f3rhydr\u00ednov\u00fdch elastom\u00e9rov. Ak n\u00e1hrada epichl\u00f3rhydr\u00ednu nie je mo\u017en\u00e1 a pou\u017e\u00edvaniu epichl\u00f3rhydr\u00ednu sa nemo\u017eno vyhn\u00fa\u0165, musia sa prija\u0165 opatrenia na zn\u00ed\u017eenie expoz\u00edcie. <\/p>\n

Naj\u00fa\u010dinnej\u0161\u00edm sp\u00f4sobom, ako zabr\u00e1ni\u0165 expoz\u00edcii epichl\u00f3rdr\u00ednu, je vyvin\u00fa\u0165 a pou\u017e\u00edva\u0165 uzavret\u00e9 syst\u00e9my. Ak to nie je mo\u017en\u00e9, mali by sa zavies\u0165 technick\u00e9 opatrenia, ako je \u00fa\u010dinn\u00e9 miestne ods\u00e1vanie vzduchu doplnen\u00e9 dobr\u00fdm vetran\u00edm pracoviska, ako aj kontrola ich \u00fa\u010dinnosti, aby sa zabezpe\u010dilo, \u017ee expoz\u00edcia sa minimalizuje na najni\u017e\u0161iu mo\u017en\u00fa technick\u00fa mieru. <\/p>\n

Vykon\u00e1vajte pravideln\u00e9 hodnotenie expoz\u00edcie, aby ste skontrolovali, \u010di s\u00fa va\u0161e zaveden\u00e9 ochrann\u00e9 opatrenia \u00fa\u010dinn\u00e9 alebo \u010di je potrebn\u00e9 prija\u0165 \u010fal\u0161ie opatrenia. Pracovn\u00edci si musia by\u0165 vedom\u00ed \u00fa\u010dinkov expoz\u00edcie a mali by by\u0165 pravidelne \u0161kolen\u00ed o kontroln\u00fdch opatreniach potrebn\u00fdch na bezpe\u010dn\u00fa pr\u00e1cu s epichlorohidr\u00ednom, aby sa zabr\u00e1nilo expoz\u00edcii. Odpor\u00fa\u010da sa zapojenie pracovn\u00e9ho lek\u00e1ra. Povzbudzujte pracovn\u00edkov, aby hl\u00e1sili v\u010dasn\u00e9 pr\u00edznaky. Okrem toho by mali by\u0165 v\u0161etci pracovn\u00edci pou\u010den\u00ed, aby si pred prest\u00e1vkou alebo vstupom do in\u00e9ho priestoru riadne umyli ruky a aby sa na konci ka\u017edej zmeny umyli a prezliekli. <\/p>\n

V pr\u00edpade potreby zabezpe\u010dte, aby pracovn\u00edci mali primeran\u00e9 prostriedky osobnej ochrany, ako je ochrann\u00fd odev a rukavice. Osobn\u00e1 ochrana by sa nemala pou\u017e\u00edva\u0165 ako jedin\u00e9 prevent\u00edvne opatrenie. \u010co najviac z uveden\u00fdch technick\u00fdch a organiza\u010dn\u00fdch opatren\u00ed mus\u00ed by\u0165 vykonan\u00fdch vopred. Okrem toho sa pri v\u00fdbere prostriedkov mus\u00ed zoh\u013eadni\u0165 anat\u00f3mia pracovn\u00edkov, ktor\u00ed ich bud\u00fa pou\u017e\u00edva\u0165, a v pr\u00edpade ochrann\u00fdch prostriedkov d\u00fdchac\u00edch ciest zalo\u017een\u00fdch na prisp\u00f4soben\u00ed tv\u00e1re sa d\u00f4razne odpor\u00fa\u010da, aby sa u ka\u017edej osoby vykonal test vhodnosti. <\/p>\n

Osobn\u00e1 ochrana by sa mala pou\u017e\u00edva\u0165 len v krajnom pr\u00edpade a len do\u010dasne, po vy\u010derpan\u00ed mo\u017en\u00fdch technick\u00fdch rie\u0161en\u00ed. Pracovn\u00edci by mali absolvova\u0165 potrebn\u00e9 \u0161kolenia a z\u00edska\u0165 inform\u00e1cie o spr\u00e1vnom pou\u017e\u00edvan\u00ed a \u00fadr\u017ebe OOPP. <\/p>\n

Odkazy: ECHA, CLP (Klasifik\u00e1cia, ozna\u010dovanie a balenie), IARC, ICSC, IOM<\/em><\/p>\n","protected":false},"template":"","carcinogens":[5747],"class_list":["post-94744","fact","type-fact","status-publish","hentry","carcinogens-epichlorohydrin"],"yoast_head":"\nEpichl\u00f3rhydr\u00edn - %<\/title>\n<meta name=\"description\" content=\"Be aware of what you work with! We collected all the important information these causing substances in easy-to-understand factsheets.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/stopcarcinogensatwork.eu\/sk\/fact\/epichlorohydrin\/\" \/>\n<meta property=\"og:locale\" content=\"sk_SK\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Epichl\u00f3rhydr\u00edn\" \/>\n<meta property=\"og:description\" content=\"Be aware of what you work with! 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