{"id":57890,"date":"2025-03-18T07:29:25","date_gmt":"2025-03-18T07:29:25","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/oximes\/"},"modified":"2025-06-13T13:27:36","modified_gmt":"2025-06-13T13:27:36","slug":"oximes","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/tr\/fact\/oximes\/","title":{"rendered":"Oksimler"},"content":{"rendered":"

AB’de 700.000 kadar i\u015f\u00e7inin oksimlere maruz kald\u0131\u011f\u0131 tahmin edilmektedir. Oksimler s\u0131v\u0131 boyalarda ve kaplamalarda (cilalanmay\u0131 \u00f6nleyici maddeler olarak i\u015flev g\u00f6r\u00fcrler) ve baz\u0131 silan bazl\u0131 dolgu macunlar\u0131nda kullan\u0131l\u0131r. U\u00e7ucu olduklar\u0131ndan, maruziyetin ana yolu solumad\u0131r. <\/p><\/blockquote>\n

Oksimler bir madde ailesini tan\u0131mlar. Boya, vernik ve dolgu macunlar\u0131nda kullan\u0131lan oksimler Metiletilketoksim veya 2-b\u00fctanon oksim (MEKO) ve aseton oksim S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama y\u00f6netmeli\u011fine g\u00f6re kanserojen kategori 1B olarak s\u0131n\u0131fland\u0131r\u0131lm\u0131\u015ft\u0131r. MEKO, uzun s\u00fcreli veya tekrarlanan maruziyette \u00fcst solunum yolu (STOT SE 1, H370) ve kan sistemi (STOT RE 2, H373) \u00fczerindeki etkileri ile spesifik hedef organ toksisitesi i\u00e7in ayr\u0131ca s\u0131n\u0131fland\u0131r\u0131lm\u0131\u015ft\u0131r. Kan sistemi \u00fczerindeki benzer etkiler aseton oksim ve di\u011fer oksimler i\u00e7in de g\u00f6zlemlenmi\u015ftir. <\/p>\n

Risklerin olu\u015ftu\u011fu yerler<\/h2>\n

Mesleki maruziyet esas olarak solventler buharla\u015ft\u0131\u011f\u0131nda s\u0131v\u0131 boyalar\u0131n ve kaplamalar\u0131n uygulama a\u015famas\u0131nda meydana gelir. Tipik olarak, boya ve kaplamalar\u0131n uygulanmas\u0131, i\u015f\u00e7inin nefes alma b\u00f6lgesinde olan g\u00f6rme alan\u0131nda ger\u00e7ekle\u015fir, bu nedenle buharlara maruz kalma y\u00fcksektir. Oksim salan silanlar s\u00f6z konusu oldu\u011funda, oksimler, dolgu macunlar\u0131 tamamen k\u00fcrlenene kadar k\u00fcrlenme a\u015famas\u0131nda s\u00fcrekli olarak sal\u0131n\u0131r. Boyama ve vernikleme sekt\u00f6r\u00fcnde ve motorlu ara\u00e7lar\u0131n p\u00fcsk\u00fcrt\u00fclmesi ve boyanmas\u0131nda y\u00fcksek maruziyetler beklenebilir. Sonu\u00e7 olarak, oksimlere maruz kalma riski y\u00fcksek olan meslekler boyac\u0131lar, motorlu ta\u015f\u0131t tamircileri (boya yaparken) ve ayn\u0131 zamanda oksim salan dolgu macunlar\u0131 kullan\u0131rken tesisat\u00e7\u0131lar ve tesisat\u00e7\u0131lard\u0131r. Ayr\u0131ca, di\u011fer meslekler, oksimler i\u00e7eren \u00fcr\u00fcnlerin daha \u00f6nce kullan\u0131ld\u0131\u011f\u0131 ve hala buharla\u015fmakta oldu\u011fu \u00e7al\u0131\u015fma alanlar\u0131na girdiklerinde risk alt\u0131nda olabilirler. <\/p>\n

Madde hakk\u0131nda daha fazla bilgi<\/h2>\n

Oksimler renksiz, u\u00e7ucu ve aromatik kokulu s\u0131v\u0131lard\u0131r. En yayg\u0131n kullan\u0131lan oksimler 2-butanon oksim (MEKO), aseton oksim, 2-pentanon oksim (MPKO) ve 4-metifentanon oksimdir (MIBKO). Bununla birlikte, neredeyse hi\u00e7bir zaman saf halde kullan\u0131lmazlar, ancak d\u00fc\u015f\u00fck konsantrasyonlarda (genellikle < % 1) (\u00e7o\u011funlukla alkil) boyalarda ve kaplamalarda cilalanmay\u0131 \u00f6nleyici maddeler olarak veya oksim salan silan dolgu macunlar\u0131nda ba\u011fl\u0131 formda kullan\u0131l\u0131rlar. <\/p>\n

Olu\u015fabilecek tehlikeler<\/h2>\n

\u015eimdiye kadar herhangi bir oksimin toksikolojik etkilerine ili\u015fkin insan epidemiyolojik verisi mevcut de\u011fildir. Hayvan \u00e7al\u0131\u015fmalar\u0131nda, oksimlere oral veya inhalasyon yoluyla maruz kal\u0131nd\u0131ktan sonra ana hedef organlar karaci\u011fer, dalak ve kan sistemidir. Ayr\u0131ca, MEKO i\u00e7in ge\u00e7ici narkotik etkiler ve deride tahri\u015f g\u00f6zlenmi\u015ftir. MEKO \u201cya dermal maruziyetten sonra alerjik cilt reaksiyonlar\u0131n\u0131n m\u00fcmk\u00fcn oldu\u011fu unutulmamal\u0131d\u0131r. Bug\u00fcne kadar sadece MEKO ve aseton oksim Carc. 1B (insanlar i\u00e7in kanserojen oldu\u011fu varsay\u0131lan) olarak uyumla\u015ft\u0131r\u0131lm\u0131\u015ft\u0131r. MEKO ve aseton oksim i\u00e7in alternatif oksimler olarak kullan\u0131lan MPKO, MIBKO ve sikloheksanon oksim i\u00e7in, bug\u00fcne kadar kanserojen olarak bir CLH s\u0131n\u0131fland\u0131rmas\u0131n\u0131 hakl\u0131 \u00e7\u0131karacak kar\u015f\u0131l\u0131k gelen veri yoktur. MEKO\u201d nun solunmas\u0131ndan sonra hayvanlarda karaci\u011fer kanseri geli\u015fmi\u015ftir ve enzimatik yolak insanlarda da varsay\u0131labilir. <\/p>\n

\u015eu anda, MEKO maruziyetine ve olas\u0131 bir gecikme s\u00fcresine ba\u011fl\u0131 olarak insanlarda karaci\u011fer kanserine ili\u015fkin kan\u0131tlar eksiktir.<\/strong><\/p>\n

Yapabilecekleriniz<\/h2>\n

Maruziyeti ve potansiyel karaci\u011fer kanserini \u00f6nlemenin en etkili yolu, daha g\u00fcvenli, oksim i\u00e7ermeyen alternatiflerle ikame etmektir. Boya ve verniklerdeki oksimler i\u00e7in, su bazl\u0131 boyalar ve akrilik veya poli\u00fcretan (PU) sistemler gibi alternatif boya sistemleri bir se\u00e7enek olabilir. Solvent bazl\u0131 boyalar i\u00e7in alternatif cilalanma \u00f6nleyici maddeler piyasadad\u0131r ve amin bile\u015fikleri i\u00e7erir. Silikon dolgu macunlar\u0131 i\u00e7in, asetoksi-, benzamid-, amin-, alkoksi- ve laktat ester sistemleri olarak oksim i\u00e7ermeyen alternatifler mevcuttur. Alternatif bazl\u0131 (\u00f6rne\u011fin, poli\u00fcretan veya Silan Sonland\u0131r\u0131lm\u0131\u015f Polimer (STP)) silikon mastikler de uygulanabilir. Oksimlerin ikamesinin m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 ve oksim kullan\u0131m\u0131ndan ka\u00e7\u0131n\u0131lamad\u0131\u011f\u0131 durumlarda, maruziyeti azaltmak i\u00e7in \u00f6nlemler al\u0131nmal\u0131d\u0131r. Maruziyetten ka\u00e7\u0131nman\u0131n en etkili yolu kapal\u0131 sistemler geli\u015ftirmek ve kullanmakt\u0131r. Bunun m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 durumlarda, boyalardan veya dolgu macunlar\u0131ndan kaynaklanan oksim buharlar\u0131na maruz kalman\u0131n teknik olarak m\u00fcmk\u00fcn oldu\u011funca en aza indirilmesini sa\u011flamak i\u00e7in etkili yerel egzoz havaland\u0131rmas\u0131 veya i\u015fyerinin iyi havaland\u0131r\u0131lmas\u0131 gibi teknik \u00f6nlemler uygulanmal\u0131 ve bunlar\u0131n etkinli\u011fi kontrol edilmelidir.
\nUygulad\u0131\u011f\u0131n\u0131z koruyucu \u00f6nlemlerin etkili olup olmad\u0131\u011f\u0131n\u0131 veya ba\u015fka \u00f6nlemlerin al\u0131nmas\u0131 gerekip gerekmedi\u011fini kontrol etmek i\u00e7in d\u00fczenli maruz kalma de\u011ferlendirmeleri uygulay\u0131n. \u00c7al\u0131\u015fanlar maruziyetin potansiyel etkilerinin fark\u0131nda olmal\u0131 ve maruziyeti \u00f6nlemek i\u00e7in oksimler ile g\u00fcvenli bir \u015fekilde \u00e7al\u0131\u015fmak i\u00e7in gerekli kontrol \u00f6nlemleri konusunda d\u00fczenli olarak e\u011fitilmelidir. Ba\u015f d\u00f6nmesi, cilt tahri\u015fi ve cilt alerjileri gibi erken belirtileri bildirmeleri i\u00e7in te\u015fvik edilmelidirler. Bir i\u015fyeri hekiminin dahil edilmesi tavsiye edilir. Ayr\u0131ca, \u00e7al\u0131\u015fanlar\u0131 etkili hijyen \u00f6nlemleri konusunda e\u011fitin.<\/p>\n

Gerekirse, \u00e7al\u0131\u015fanlar\u0131n koruyucu giysi ve eldiven gibi yeterli ki\u015fisel koruyucu ekipmana sahip oldu\u011fundan emin olun. Ki\u015fisel koruyucu ekipman (KKE) yaln\u0131zca son \u00e7are olarak kullan\u0131lmal\u0131 ve olas\u0131 teknik \u00e7\u00f6z\u00fcmler t\u00fckendikten sonra yaln\u0131zca ge\u00e7ici olarak d\u00fc\u015f\u00fcn\u00fclmelidir. Yeniden kullan\u0131labilir KKD kullan\u0131l\u0131yorsa, \u00f6ng\u00f6r\u00fclen \u015fekilde (en son solunum ekipman\u0131) \u00e7\u0131kar\u0131lmas\u0131na, d\u00fczenli olarak temizlenmesine ve kirlenmeyi \u00f6nleyecek \u015fekilde saklanmas\u0131na dikkat edin. <\/p>\n

Referanslar: BAuA, S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama, BG BAU<\/em><\/p>\n","protected":false},"template":"","carcinogens":[2584],"class_list":["post-57890","fact","type-fact","status-publish","hentry","carcinogens-oximes-tr"],"yoast_head":"\nOksimler - STOP carcinogens at work<\/title>\n<meta name=\"description\" content=\"AB'de 700.000 kadar i\u015f\u00e7inin oksimlere maruz kald\u0131\u011f\u0131 tahmin edilmektedir. 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