{"id":57890,"date":"2025-03-18T07:29:25","date_gmt":"2025-03-18T07:29:25","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/oximes\/"},"modified":"2026-06-13T11:31:34","modified_gmt":"2026-06-13T11:31:34","slug":"oximes","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/tr\/fact\/oximes\/","title":{"rendered":"Oksimler"},"content":{"rendered":"

AB’de 700.000’e yak\u0131n \u00e7al\u0131\u015fan\u0131n oksimlere maruz kald\u0131\u011f\u0131 tahmin edilmektedir. Oksimler, s\u0131v\u0131 boya ve kaplamalarda (burada kabuklanma \u00f6nleyici madde olarak i\u015flev g\u00f6r\u00fcrler) ve baz\u0131 silan bazl\u0131 s\u0131zd\u0131rmazl\u0131k maddelerinde kullan\u0131lmaktad\u0131r. U\u00e7ucu maddeler olduklar\u0131 i\u00e7in, exposureun ba\u015fl\u0131ca yolu solunum yoludur. <\/p><\/blockquote>\n

Oksimler, bir madde grubunu ifade eder. Boya, vernik ve s\u0131zd\u0131rmazl\u0131k maddelerinde kullan\u0131lan metiletilketoksim veya 2-butanon oksim (MEKO) ile aseton oksim, S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama Y\u00f6netmeli\u011fi uyar\u0131nca 1B kategorisi carcinogenler olarak s\u0131n\u0131fland\u0131r\u0131lm\u0131\u015ft\u0131r. MEKO ayr\u0131ca, uzun s\u00fcreli veya tekrarlanan exposure durumunda \u00fcst solunum yollar\u0131na (STOT SE 1, H370) ve kan sistemine (STOT RE 2, H373) etkileri nedeniyle spesifik hedef organ toksisitesi a\u00e7\u0131s\u0131ndan s\u0131n\u0131fland\u0131r\u0131lm\u0131\u015ft\u0131r. Aseton oksim ve di\u011fer oksimler i\u00e7in de kan sistemi \u00fczerinde benzer etkiler g\u00f6zlemlenmi\u015ftir. <\/p>\n

Risklerin olu\u015ftu\u011fu yerler<\/h2>\n

Mesleki exposure, primarily occurs during the application phase of liquid paints and coatings, as solvents evaporate. Generally, application of paints and coatings occurs in the worker\u2019s visual field, which is in the breathing zone, so exposure to vapors is high. Oksim salan silanlarda, s\u0131zd\u0131rmazl\u0131k maddeleri tamamen k\u00fcrlenene kadar k\u00fcrleme a\u015famas\u0131 boyunca s\u00fcrekli olarak oksimler sal\u0131n\u0131r. Boya ve vernikleme sekt\u00f6r\u00fcnde ve motorlu ta\u015f\u0131tlar\u0131n p\u00fcsk\u00fcrtme ve boyama i\u015flemlerinde y\u00fcksek d\u00fczeyde exposure beklenebilir. Sonu\u00e7 olarak, oksimlere maruz kalma riski y\u00fcksek meslekler aras\u0131nda boyac\u0131lar, motorlu ta\u015f\u0131t tamircileri (boyama s\u0131ras\u0131nda) ve ayr\u0131ca oksim salan s\u0131zd\u0131rmazl\u0131k maddeleri kullanan tesisat\u00e7\u0131lar ve montajc\u0131lar yer al\u0131r. Ayr\u0131ca, daha \u00f6nce oksim i\u00e7eren \u00fcr\u00fcnlerin kullan\u0131ld\u0131\u011f\u0131 ve bu \u00fcr\u00fcnlerin hala buharla\u015ft\u0131\u011f\u0131 \u00e7al\u0131\u015fma alanlar\u0131na giren di\u011fer meslek gruplar\u0131 da risk alt\u0131nda olabilir. <\/p>\n

Madde hakk\u0131nda daha fazla bilgi<\/h2>\n

Oksimler, aromatik kokulu, renksiz ve u\u00e7ucu s\u0131v\u0131lard\u0131r. En yayg\u0131n olarak kullan\u0131lan oksimler aras\u0131nda 2-butanon oksim (MEKO), aseton oksim, 2-pentanon oksim (MPKO) ve 4-metilpentanon oksim (MIBKO) bulunur. Ancak, bunlar neredeyse hi\u00e7bir zaman saf halde kullan\u0131lmazlar; bunun yerine, (\u00e7o\u011funlukla alkil) boya ve kaplamalarda kabuklanmay\u0131 \u00f6nleyici maddeler olarak d\u00fc\u015f\u00fck konsantrasyonlarda (genellikle % < %1) veya oksim salan silan s\u0131zd\u0131rmazl\u0131k maddelerinde ba\u011fl\u0131 halde kullan\u0131l\u0131rlar. <\/p>\n

Olu\u015fabilecek tehlikeler<\/h2>\n

\u015eu ana kadar, herhangi bir oksimin toksikolojik etkileriyle ilgili insan epidemiyolojisi verisi bulunmamaktad\u0131r. Hayvan \u00e7al\u0131\u015fmalar\u0131nda, oksimlere oral yolla veya solunum yoluyla maruz kal\u0131nd\u0131ktan sonra ana hedef organlar karaci\u011fer, dalak ve kan sistemidir. Ayr\u0131ca, MEKO i\u00e7in ge\u00e7ici narkotik etkiler ve cilt tahri\u015fi g\u00f6zlemlenmi\u015ftir. MEKO’ya dermal exposure’\u0131n ard\u0131ndan alerjik cilt reaksiyonlar\u0131n\u0131n ortaya \u00e7\u0131kabilece\u011fi unutulmamal\u0131d\u0131r. Bug\u00fcne kadar, yaln\u0131zca MEKO ve aseton oksim, Carc. 1B (insanlar i\u00e7in muhtemel carcinogen) olarak uyumla\u015ft\u0131r\u0131lm\u0131\u015ft\u0131r. MEKO ve aseton oksim i\u00e7in alternatif oksimler olarak kullan\u0131lan MPKO, MIBKO ve sikloheksanon oksim i\u00e7in, \u015fu ana kadar carcinogen olarak CLH s\u0131n\u0131fland\u0131rmas\u0131n\u0131 hakl\u0131 g\u00f6sterecek ilgili veri bulunmamaktad\u0131r. MEKO’nun solunmas\u0131ndan sonra hayvanlarda karaci\u011fer kanseri geli\u015fmi\u015ftir ve enzimatik yolun insanlarda da oldu\u011fu varsay\u0131labilir. <\/p>\n

\u015eu anda, insanlarda MEKO exposure’a dayal\u0131 karaci\u011fer kanseri ve olas\u0131 bir latans d\u00f6nemi ile ilgili kan\u0131tlar bulunmamaktad\u0131r.<\/strong><\/p>\n

Yapabilecekleriniz<\/h2>\n

Exposure and potential liver cancer can be prevented by replacing them with safer, oxime-free alternatives. For oximes in paints and varnishes, water-based paints and acrylic or polyurethane (PU) systems can be considered as alternative paint systems. Solvent bazl\u0131 boyalar i\u00e7in alternatif kabuklanma \u00f6nleyici maddeler piyasada mevcuttur ve amin bile\u015fikleri i\u00e7erir. Silikon s\u0131zd\u0131rmazl\u0131k maddeleri i\u00e7in, asetoksi, benzamid, amin, alkoksi ve laktat ester sistemleri gibi oksimler i\u00e7ermeyen alternatifler mevcuttur. Alternatif bazlara sahip silikon s\u0131zd\u0131rmazl\u0131k maddeleri (\u00f6rn. poli\u00fcretan veya Silan Sonlu Polimer (STP)) de kullan\u0131labilir. Oksimlerin ikame edilmesinin m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 ve oksimlerin kullan\u0131m\u0131n\u0131n ka\u00e7\u0131n\u0131lmaz oldu\u011fu durumlarda, exposure\u2019\u0131 azaltmak i\u00e7in \u00f6nlemler al\u0131nmal\u0131d\u0131r. Maruziyeti \u00f6nlemenin en etkili yolu, kapal\u0131 sistemler geli\u015ftirmek ve kullanmakt\u0131r. Bunun m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 durumlarda, boya veya s\u0131zd\u0131rmazl\u0131k maddelerinden kaynaklanan oksim buharlar\u0131na maruziyeti teknik olarak m\u00fcmk\u00fcn oldu\u011funca en aza indirmek i\u00e7in, etkili yerel egzoz havaland\u0131rmas\u0131 veya i\u015fyerinin iyi havaland\u0131r\u0131lmas\u0131 gibi teknik \u00f6nlemler al\u0131nmal\u0131 ve bunlar\u0131n etkinli\u011fi kontrol edilmelidir.
\nY\u00fcr\u00fcrl\u00fckteki koruyucu \u00f6nlemlerin etkili olup olmad\u0131\u011f\u0131n\u0131 veya ba\u015fka \u00f6nlemlerin al\u0131nmas\u0131 gerekip gerekmedi\u011fini kontrol etmek i\u00e7in d\u00fczenli exposure de\u011ferlendirmeleri yap\u0131n. \u00c7al\u0131\u015fanlar, exposure’un olas\u0131 etkilerinin fark\u0131nda olmal\u0131 ve exposure’u \u00f6nlemek i\u00e7in oksimlerle g\u00fcvenli bir \u015fekilde \u00e7al\u0131\u015fmak i\u00e7in gerekli kontrol \u00f6nlemleri konusunda d\u00fczenli olarak e\u011fitilmelidir. Ba\u015f d\u00f6nmesi, cilt tahri\u015fi ve cilt alerjileri gibi erken belirtileri bildirmeleri i\u00e7in te\u015fvik edilmelidir. Bir i\u015f sa\u011fl\u0131\u011f\u0131 hekiminin dahil edilmesi \u00f6nerilir. Ayr\u0131ca, \u00e7al\u0131\u015fanlara etkili hijyen \u00f6nlemleri konusunda e\u011fitim verin. <\/p>\n

Gerekirse, \u00e7al\u0131\u015fanlar\u0131n koruyucu giysi ve eldiven gibi uygun ki\u015fisel koruma donan\u0131m\u0131na sahip oldu\u011fundan emin olun. Ki\u015fisel koruma donan\u0131m\u0131 (KKD) yaln\u0131zca son \u00e7are olarak kullan\u0131lmal\u0131 ve olas\u0131 teknik \u00e7\u00f6z\u00fcmler t\u00fckenmi\u015fse ge\u00e7ici olarak d\u00fc\u015f\u00fcn\u00fclmelidir. Yeniden kullan\u0131labilir KKD kullan\u0131l\u0131yorsa, \u00f6ng\u00f6r\u00fclen \u015fekilde (solunum ekipman\u0131 en son) \u00e7\u0131kar\u0131lmas\u0131na, d\u00fczenli olarak temizlenmesine ve kontaminasyonun \u00f6nlenece\u011fi \u015fekilde saklanmas\u0131na \u00f6zen g\u00f6sterin. <\/p>\n

Kaynaklar: BAuA, S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama<\/em><\/p>\n","protected":false},"template":"","carcinogens":[2584],"class_list":["post-57890","fact","type-fact","status-publish","hentry","carcinogens-oximes-tr"],"yoast_head":"\nOksimler - STOP carcinogens at work<\/title>\n<meta name=\"description\" content=\"AB'de 700.000'e yak\u0131n \u00e7al\u0131\u015fan\u0131n oksimlere maruz kald\u0131\u011f\u0131 tahmin edilmektedir. 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