{"id":57890,"date":"2025-03-18T07:29:25","date_gmt":"2025-03-18T07:29:25","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/oximes\/"},"modified":"2026-11-04T22:20:13","modified_gmt":"2026-11-04T22:20:13","slug":"oximes","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/tr\/fact\/oximes\/","title":{"rendered":"Oksimler"},"content":{"rendered":"<blockquote><p>AB&#8217;de 700.000&#8217;e yak\u0131n \u00e7al\u0131\u015fan\u0131n oksimlere maruz kald\u0131\u011f\u0131 tahmin edilmektedir. Oksimler, s\u0131v\u0131 boya ve kaplamalarda (burada kabuklanma \u00f6nleyici madde olarak i\u015flev g\u00f6r\u00fcrler) ve baz\u0131 silan bazl\u0131 s\u0131zd\u0131rmazl\u0131k maddelerinde kullan\u0131lmaktad\u0131r. U\u00e7ucu olduklar\u0131 i\u00e7in, exposureun ba\u015fl\u0131ca yolu solunumdur.  <\/p><\/blockquote>\n<p>Oksimler bir madde ailesini tan\u0131mlar. Boya, vernik ve s\u0131zd\u0131rmazl\u0131k maddelerinde kullan\u0131lan metiletilketoksim veya 2-butanon oksim (MEKO) ve aseton oksim, S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama Y\u00f6netmeli\u011fi&#8217;ne g\u00f6re 1B kategorisi carcinogenler olarak s\u0131n\u0131fland\u0131r\u0131lm\u0131\u015ft\u0131r. MEKO ayr\u0131ca, uzun s\u00fcreli veya tekrarlanan exposure durumunda \u00fcst solunum yollar\u0131na (STOT SE 1, H370) ve kan sistemine (STOT RE 2, H373) etkileri nedeniyle spesifik hedef organ toksisitesi a\u00e7\u0131s\u0131ndan s\u0131n\u0131fland\u0131r\u0131lm\u0131\u015ft\u0131r. Aseton oksim ve di\u011fer oksimler i\u00e7in de kan sistemi \u00fczerinde benzer etkiler g\u00f6zlemlenmi\u015ftir.   <\/p>\n<h2>Risklerin ortaya \u00e7\u0131kt\u0131\u011f\u0131 yerler<\/h2>\n<p>Mesleki exposure, esas olarak s\u0131v\u0131 boya ve kaplamalar\u0131n uygulama a\u015famas\u0131nda, solventler buharla\u015f\u0131rken meydana gelir. Tipik olarak, boya ve kaplamalar\u0131n uygulanmas\u0131, \u00e7al\u0131\u015fan\u0131n solunum b\u00f6lgesinde bulunan g\u00f6r\u00fc\u015f alan\u0131nda ger\u00e7ekle\u015fir, bu nedenle buharlara exposure y\u00fcksek olur. Oksim salan silanlar s\u00f6z konusu oldu\u011funda, s\u0131zd\u0131rmazl\u0131k maddeleri tamamen k\u00fcrlenene kadar k\u00fcrleme a\u015famas\u0131 boyunca oksimler s\u00fcrekli olarak sal\u0131n\u0131r. Boya ve vernikleme sekt\u00f6r\u00fcnde ve motorlu ta\u015f\u0131tlar\u0131n p\u00fcsk\u00fcrtme ve boyama i\u015flemlerinde y\u00fcksek exposure beklenebilir. Sonu\u00e7 olarak, oksimlere exposure riski y\u00fcksek meslekler aras\u0131nda boyac\u0131lar, motorlu ta\u015f\u0131t tamircileri (boyama s\u0131ras\u0131nda), ayn\u0131 zamanda oksim salan s\u0131zd\u0131rmazl\u0131k maddeleri kullanan tesisat\u00e7\u0131lar ve montajc\u0131lar yer al\u0131r. Ayr\u0131ca, daha \u00f6nce oksim i\u00e7eren \u00fcr\u00fcnlerin kullan\u0131ld\u0131\u011f\u0131 ve hala buharla\u015ft\u0131\u011f\u0131 \u00e7al\u0131\u015fma alanlar\u0131na giren di\u011fer meslek gruplar\u0131 da risk alt\u0131nda olabilir.     <\/p>\n<h2>Madde hakk\u0131nda daha fazla bilgi<\/h2>\n<p>Oksimler, aromatik kokulu, renksiz ve u\u00e7ucu s\u0131v\u0131lard\u0131r. En yayg\u0131n olarak kullan\u0131lan oksimler aras\u0131nda 2-butanon oksim (MEKO), aseton oksim, 2-pentanon oksim (MPKO) ve 4-metilpentanon oksim (MIBKO) bulunur. Ancak, bunlar neredeyse hi\u00e7bir zaman saf halde kullan\u0131lmazlar; bunun yerine, (\u00e7o\u011funlukla alkil) boya ve kaplamalarda kabuklanmay\u0131 \u00f6nleyici maddeler olarak d\u00fc\u015f\u00fck konsantrasyonlarda (genellikle % &lt; %1) veya oksim salan silan s\u0131zd\u0131rmazl\u0131k maddelerinde ba\u011fl\u0131 halde kullan\u0131l\u0131rlar.  <\/p>\n<h2>Olu\u015fabilecek tehlikeler<\/h2>\n<p>\u015eu ana kadar, herhangi bir oksimin toksikolojik etkileriyle ilgili insan epidemiyolojisi verisi bulunmamaktad\u0131r. Hayvan \u00e7al\u0131\u015fmalar\u0131nda, oksimlere oral yolla veya solunum yoluyla exposure sonras\u0131 ana hedef organlar karaci\u011fer, dalak ve kan sistemidir. Ayr\u0131ca, MEKO i\u00e7in ge\u00e7ici narkotik etkiler ve cilt tahri\u015fi g\u00f6zlemlenmi\u015ftir. MEKO&#8217;ya dermal exposure sonras\u0131 alerjik cilt reaksiyonlar\u0131n\u0131n m\u00fcmk\u00fcn oldu\u011fu unutulmamal\u0131d\u0131r. Bug\u00fcne kadar, yaln\u0131zca MEKO ve aseton oksim, Carc. 1B (insanlar i\u00e7in muhtemel carcinogen) olarak uyumla\u015ft\u0131r\u0131lm\u0131\u015ft\u0131r. MEKO ve aseton oksim i\u00e7in alternatif oksimler olarak kullan\u0131lan MPKO, MIBKO ve sikloheksanon oksim i\u00e7in, \u015fu ana kadar carcinogen olarak CLH s\u0131n\u0131fland\u0131rmas\u0131n\u0131 hakl\u0131 g\u00f6sterecek ilgili veri bulunmamaktad\u0131r. MEKO&#8217;nun solunmas\u0131ndan sonra hayvanlarda karaci\u011fer kanseri geli\u015fmi\u015ftir ve enzimatik yolun insanlarda da oldu\u011fu varsay\u0131labilir.       <\/p>\n<p><strong>\u015eu anda, insanlarda MEKO exposure&#8217;a dayal\u0131 karaci\u011fer kanseri ve olas\u0131 bir latans d\u00f6nemi ile ilgili kan\u0131tlar bulunmamaktad\u0131r.<\/strong><\/p>\n<h2>Yapabilecekleriniz<\/h2>\n<p>Exposure ve potansiyel karaci\u011fer kanserini \u00f6nlemenin en etkili yolu, daha g\u00fcvenli, oksim i\u00e7ermeyen alternatiflerle ikame etmektir. Boya ve verniklerdeki oksimler i\u00e7in, su bazl\u0131 boyalar ve akrilik veya poli\u00fcretan (PU) sistemler gibi alternatif boya sistemleri bir se\u00e7enek olabilir. Solvent bazl\u0131 boyalar i\u00e7in alternatif kabuklanma \u00f6nleyici maddeler piyasada mevcuttur ve amin bile\u015fikleri i\u00e7erir. Silikon s\u0131zd\u0131rmazl\u0131k maddeleri i\u00e7in, asetoksi-, benzamid-, amin-, alkoksi- ve laktat ester sistemleri gibi oksim i\u00e7ermeyen alternatifler mevcuttur. Alternatif bazlara sahip silikon s\u0131zd\u0131rmazl\u0131k maddeleri (\u00f6rn. poli\u00fcretan veya Silan Sonlu Polimer (STP)) de uygulanabilir. Oksimlerin ikamesinin m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 ve oksim kullan\u0131m\u0131ndan ka\u00e7\u0131n\u0131lamad\u0131\u011f\u0131 durumlarda, exposure&#8217;\u0131 azaltmak i\u00e7in \u00f6nlemler al\u0131nmal\u0131d\u0131r. Exposure&#8217;\u0131 \u00f6nlemenin en etkili yolu, kapal\u0131 sistemler geli\u015ftirmek ve kullanmakt\u0131r. Bunun m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 durumlarda, boya veya s\u0131zd\u0131rmazl\u0131k maddelerinden kaynaklanan oksim buharlar\u0131na exposure&#8217;\u0131n teknik olarak m\u00fcmk\u00fcn oldu\u011funca en aza indirilmesini sa\u011flamak i\u00e7in etkili yerel egzoz havaland\u0131rmas\u0131 veya i\u015fyerinin iyi havaland\u0131r\u0131lmas\u0131 gibi teknik \u00f6nlemler uygulanmal\u0131 ve bunlar\u0131n etkinli\u011fi kontrol edilmelidir.<br \/>\nMevcut koruyucu \u00f6nlemlerinizin etkili olup olmad\u0131\u011f\u0131n\u0131 veya ba\u015fka \u00f6nlemlerin al\u0131nmas\u0131 gerekip gerekmedi\u011fini kontrol etmek i\u00e7in d\u00fczenli exposure de\u011ferlendirmeleri uygulay\u0131n. \u00c7al\u0131\u015fanlar\u0131n exposure&#8217;\u0131n potansiyel etkilerinin fark\u0131nda olmas\u0131 ve exposure&#8217;\u0131 \u00f6nlemek i\u00e7in oksimlerle g\u00fcvenli bir \u015fekilde \u00e7al\u0131\u015fmak i\u00e7in gerekli kontrol \u00f6nlemleri konusunda d\u00fczenli olarak e\u011fitilmesi gerekir. Ba\u015f d\u00f6nmesi, cilt tahri\u015fi ve cilt alerjileri gibi erken semptomlar\u0131 bildirmeleri te\u015fvik edilmelidir. Bir i\u015f sa\u011fl\u0131\u011f\u0131 hekiminin dahil edilmesi \u00f6nerilir. Ayr\u0131ca, \u00e7al\u0131\u015fanlar\u0131 etkili hijyen \u00f6nlemleri konusunda e\u011fitin.           <\/p>\n<p>Gerekirse, \u00e7al\u0131\u015fanlar\u0131n koruyucu giysi ve eldiven gibi yeterli ki\u015fisel koruma ekipman\u0131na sahip oldu\u011fundan emin olun. Ki\u015fisel koruma ekipman\u0131 (KKD) yaln\u0131zca son \u00e7are olarak kullan\u0131lmal\u0131 ve olas\u0131 teknik \u00e7\u00f6z\u00fcmler t\u00fckendikten sonra ge\u00e7ici olarak d\u00fc\u015f\u00fcn\u00fclmelidir. Yeniden kullan\u0131labilir KKD kullan\u0131l\u0131yorsa, \u00f6ng\u00f6r\u00fclen \u015fekilde (solunum ekipman\u0131 en son) \u00e7\u0131kar\u0131lmas\u0131na, d\u00fczenli olarak temizlenmesine ve kontaminasyonun \u00f6nlenece\u011fi \u015fekilde saklanmas\u0131na \u00f6zen g\u00f6sterin.  <\/p>\n<p><em>Kaynaklar: BAuA, S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama<\/em><\/p>\n","protected":false},"template":"","carcinogens":[2584],"class_list":["post-57890","fact","type-fact","status-publish","hentry","carcinogens-oximes-tr"],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v28.8 (Yoast SEO v28.8) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>Oksimler - \u0130\u015fyerinde carcinogen maddeleri DURDURUN<\/title>\n<meta name=\"description\" content=\"AB&#039;de 700.000&#039;e yak\u0131n \u00e7al\u0131\u015fan\u0131n oksimlere maruz kald\u0131\u011f\u0131 tahmin edilmektedir. 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