{"id":57897,"date":"2024-01-04T09:22:40","date_gmt":"2024-01-04T09:22:40","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/azodyes\/"},"modified":"2026-06-30T13:06:54","modified_gmt":"2026-06-30T13:06:54","slug":"azodyes","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/tr\/fact\/azodyes\/","title":{"rendered":"Azo boyalar\u0131"},"content":{"rendered":"<blockquote><p>AB\u2019de, aromatik aminlere ayr\u0131\u015fabilen azo boyalara maruz kalan \u00e7al\u0131\u015fanlar\u0131n mevcut say\u0131s\u0131na ili\u015fkin tahminler mevcut de\u011fildir. Exposure to azo dyes may occur where azo dyes are produced and used for coloring or indicator purposes. Skin exposure is the most important form of exposure as liquid formulations are now widespread. In some individual cases, exposure by inhalation may also occur.   <\/p><\/blockquote>\n<p>Azo boyalar\u0131n, aromatik aminlere ayr\u0131\u015fabilmeleri nedeniyle kansere yol a\u00e7t\u0131\u011f\u0131 \u015f\u00fcphelenilmektedir. Baz\u0131 aromatik aminler bilinen carcinogen maddelerdir (S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama\u2019ya g\u00f6re kategori 1A); \u00f6rne\u011fin, 4-aminobifenil, benzidin, 4-kloro-o-toluidin, 2-naftilamin gibi; ya da insanlar i\u00e7in carcinogen oldu\u011fu varsay\u0131lanlar (S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama&#8217;ya g\u00f6re kategori 1B), \u00f6rne\u011fin o-Toluidin, o-anisidin, 4-aminoazobenzen. Azo boyalardan sal\u0131nan di\u011fer aromatik aminlerin de insanlar i\u00e7in carcinogen oldu\u011fundan \u015f\u00fcphelenilmektedir.  <\/p>\n<p>Baz\u0131 aromatik aminler, mukoza de\u011fi\u015fikliklerine, kansere veya idrar yollar\u0131nda di\u011fer t\u00fcm\u00f6rlere yol a\u00e7an meslek hastal\u0131klar\u0131yla ili\u015fkilendirilmektedir.<\/p>\n<h2>Risklerin olu\u015ftu\u011fu yerler<\/h2>\n<p>Genel olarak, azo boyalar\u0131 end\u00fcstride plastik ve kau\u00e7uk \u00fcr\u00fcnleri, ah\u015fap, ka\u011f\u0131t, boyalar ve cilalar\u0131n renklendirilmesinde yayg\u0131n olarak kullan\u0131lmaktad\u0131r; bunun yan\u0131 s\u0131ra tekstil lifleri, kozmetik \u00fcr\u00fcnleri, ila\u00e7lar ve hatta g\u0131da gibi t\u00fcketim \u00fcr\u00fcnlerinin renklendirilmesinde de kullan\u0131lmaktad\u0131r. Daha az yayg\u0131n bir uygulama alan\u0131 ise t\u0131bbi veya biyolojik ara\u015ft\u0131rmalar olabilir; \u00f6rne\u011fin, mikroskopi i\u00e7in kullan\u0131lan renklendiriciler. <\/p>\n<p>Deri veya tekstil boyamada eskiden yayg\u0131n olarak kullan\u0131lan bu madde, Avrupa\u2019da yasaklanm\u0131\u015f ve o zamandan beri kullan\u0131m\u0131 azalm\u0131\u015ft\u0131r.<\/p>\n<p>C.I. Solvent Red 24, 164 ve 215 gibi o-Toluidin salan azo boyalar, h\u00e2l\u00e2 mineral ya\u011flar\u0131n i\u015faretlenmesinde veya metal end\u00fcstrisinde oldu\u011fu gibi tahribats\u0131z muayene y\u00f6ntemlerinde \u00e7atlak tespiti i\u00e7in boya penetranlar\u0131 olarak kullan\u0131lmaktad\u0131r. Cilt yoluyla exposure riskinin y\u00fcksek oldu\u011fu meslekler aras\u0131nda end\u00fcstriyel boyac\u0131lar, g\u00fczellik uzmanlar\u0131 ve malzeme denet\u00e7ileri yer almaktad\u0131r. <\/p>\n<h2>Madde hakk\u0131nda daha fazla bilgi<\/h2>\n<p>3000&#8217;den fazla farkl\u0131 azo bile\u015fi\u011fi bulunmaktad\u0131r. Ekonomik a\u00e7\u0131dan \u00f6nemli azo bile\u015fikleri aras\u0131nda azo renklendiriciler yer almaktad\u0131r; bunlar, uygulama ortam\u0131nda pratik olarak \u00e7\u00f6z\u00fcnmeyen azo boyalar ile \u00e7\u00f6z\u00fcn\u00fcr azo boyalar olarak alt gruplara ayr\u0131l\u0131r. <\/p>\n<p>\u0130kinci durumda, dermal exposure a\u00e7\u0131s\u0131ndan \u00f6nemli bir rol oynayan suda \u00e7\u00f6z\u00fcnen ve organik \u00e7\u00f6z\u00fcc\u00fclerde \u00e7\u00f6z\u00fcnen azo boyalar aras\u0131nda bir ayr\u0131m yap\u0131l\u0131r. Cilt \u00fczerinde bulunan \u00e7\u00f6z\u00fcnen azo boyalar, bakteriyel veya enzimatik etki sonucu, cilt yoluyla emilen \u00e7\u00f6z\u00fcnen aromatik aminlere d\u00f6n\u00fc\u015ft\u00fcr\u00fclebilir. <\/p>\n<p>Azo boyalar\u0131, asit boyalar\u0131, direkt boyalar, reaktif boyalar veya dispers boyalar gibi farkl\u0131 renk t\u00fcrlerine s\u0131n\u0131fland\u0131r\u0131labilir. Renk indeksi sisteminde, di\u011fer boyalar gibi azo boyalar da kimyasal davran\u0131\u015flar\u0131na ve renklendirmede kullan\u0131m \u015fekillerine g\u00f6re s\u0131n\u0131fland\u0131r\u0131l\u0131r; bu s\u0131n\u0131fland\u0131rma sonucunda renk indeksi ad\u0131 (C.I. genel ad\u0131) ortaya \u00e7\u0131kar. <\/p>\n<p>Aromatik aminlerin t\u00fct\u00fcn duman\u0131nda, Diesel egzoz gazlar\u0131nda, k\u00f6m\u00fcr katran\u0131ndaki safs\u0131zl\u0131klar olarak ya da kau\u00e7uk \u00fcr\u00fcnlerinin \u00fcretiminde kullan\u0131lan katk\u0131 maddelerinde de bulunabildi\u011fini ve bunun di\u011fer meslek gruplar\u0131n\u0131 da etkiledi\u011fini belirtmek \u00f6nemlidir.<\/p>\n<h2>Olu\u015fabilecek tehlikeler<\/h2>\n<p>\u00c7\u00f6z\u00fcn\u00fcr azo boyalar\u0131 esas olarak deri yoluyla emilir. Solunum yoluyla maruz kalma da rol oynayabilir. Ancak, azo boyalar\u0131n\u0131n suda \u00e7\u00f6z\u00fcn\u00fcr m\u00fc yoksa ya\u011fda \u00e7\u00f6z\u00fcn\u00fcr m\u00fc oldu\u011funa ba\u011fl\u0131 olarak, farkl\u0131 \u015fekillerde ve farkl\u0131 h\u0131zlarda emilirler.  <\/p>\n<p>Exposure to soluble azo dyes has been associated with acute toxic effects in humans, but not exposure to insoluble azo pigments. Bununla birlikte, akci\u011ferler yoluyla emildikten sonra ve \u00e7\u00f6z\u00fcnmeyen pigmentlerin boyutuna ba\u011fl\u0131 olarak, bu pigmentler, \u00f6rne\u011fin \u00f6ks\u00fcr\u00fck gibi semptomlarla ba\u015flayan, gran\u00fcler biyopersistan tozlara benzerlikler de dahil olmak \u00fczere, partik\u00fcllere \u00f6zg\u00fc etkiler geli\u015ftirebilirler. <\/p>\n<p>\u0130\u015fyerinde exposure&#8217;un, mukoza zarlar\u0131ndaki de\u011fi\u015fiklikler, kanser veya idrar yollar\u0131ndaki di\u011fer t\u00fcm\u00f6rler gibi bilinen meslek hastal\u0131klar\u0131yla en yak\u0131ndan ili\u015fkili oldu\u011fu bildirilmi\u015ftir. Ayr\u0131ca, kronik exposure&#8217;un alerjik cilt reaksiyonlar\u0131yla da ili\u015fkili oldu\u011fu d\u00fc\u015f\u00fcn\u00fclmektedir. <\/p>\n<p><strong>Exposure to aromatics and related urinary tract cancers (bladder cancer) is associated with a latency period ranging from 12 to more than 40 years<\/strong>. <strong>\u0130lgili carcinogen aminler aras\u0131nda o-Toluidin, ksenilamin, 2-naftilamin, benzidin ve 4-kloro-o-Toluidin bulunmaktad\u0131r.<\/strong><\/p>\n<h2>Yapabilecekleriniz<\/h2>\n<p>Exposure can be prevented by substituting azodicarbonamide with another compound. Piyasada, \u00f6zellikle tekstil ve g\u0131da end\u00fcstrisi i\u00e7in daha g\u00fcvenli alternatif boyalar bulunmaktad\u0131r; \u00f6rne\u011fin, alternatif do\u011fal boyalar veya mineral\/pigment boyalar. Azo boyalar\u0131n ikame edilmesinin m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 ve kullan\u0131m\u0131n\u0131n ka\u00e7\u0131n\u0131lmaz oldu\u011fu durumlarda, exposure&#8217;\u0131 azaltmaya y\u00f6nelik \u00f6nlemler al\u0131nmal\u0131d\u0131r.  <\/p>\n<p>Azo boyalar\u0131na maruz kalmay\u0131 \u00f6nlemenin en etkili yolu, kapal\u0131 sistemler geli\u015ftirmek ve kullanmakt\u0131r. Bunun m\u00fcmk\u00fcn olmad\u0131\u011f\u0131 durumlarda, exposure&#8217;un teknik olarak m\u00fcmk\u00fcn oldu\u011funca en aza indirilmesini sa\u011flamak i\u00e7in etkili yerel egzoz havaland\u0131rmas\u0131 veya i\u015fyerinin iyi havaland\u0131r\u0131lmas\u0131 gibi teknik \u00f6nlemler al\u0131nmal\u0131 ve bu \u00f6nlemlerin etkinli\u011fi kontrol edilmelidir. Tekstil end\u00fcstrisi i\u00e7in standart gerekliliklerden biri, \u00e7evre ve sa\u011fl\u0131k \u00fczerindeki etkileri en aza indirmek amac\u0131yla dikkate al\u0131nmas\u0131 gereken mevcut en iyi teknolojidir (BAT).  <\/p>\n<p>Mevcut koruyucu \u00f6nlemlerinizin etkili olup olmad\u0131\u011f\u0131n\u0131 veya ilave \u00f6nlemlerin al\u0131nmas\u0131 gerekip gerekmedi\u011fini kontrol etmek i\u00e7in d\u00fczenli exposure de\u011ferlendirmeleri ger\u00e7ekle\u015ftirin. \u00c7al\u0131\u015fanlar, exposure&#8217;un etkilerinin fark\u0131nda olmal\u0131 ve exposure&#8217;u \u00f6nlemek amac\u0131yla azo boyalarla g\u00fcvenli bir \u015fekilde \u00e7al\u0131\u015fmak i\u00e7in gerekli kontrol \u00f6nlemleri konusunda d\u00fczenli olarak e\u011fitilmelidir. Solunum sorunlar\u0131 veya cilt alerjileri gibi erken belirtileri bildirmeleri i\u00e7in te\u015fvik edilmelidir. Bir i\u015f sa\u011fl\u0131\u011f\u0131 hekiminin s\u00fcrece dahil edilmesi tavsiye edilir. Ayr\u0131ca, \u00e7al\u0131\u015fanlara etkili hijyen \u00f6nlemleri konusunda e\u011fitim verin.    <\/p>\n<p>Ana maruz kalma yolu cilt oldu\u011fu i\u00e7in, \u00e7al\u0131\u015fanlar\u0131n gerekti\u011finde koruyucu giysi ve eldiven gibi yeterli ki\u015fisel koruma donan\u0131m\u0131 sahip olmalar\u0131n\u0131 sa\u011flay\u0131n. Ki\u015fisel koruma donan\u0131m\u0131, ancak son \u00e7are olarak ve olas\u0131 teknik \u00e7\u00f6z\u00fcmler t\u00fckenmi\u015fse ge\u00e7ici bir \u00f6nlem olarak kullan\u0131lmal\u0131d\u0131r. Yeniden kullan\u0131labilir ki\u015fisel koruma donan\u0131m\u0131n, kullan\u0131mdan sonra temizlenmesi ve temiz bir yerde saklanmas\u0131 \u00f6nemlidir.  <\/p>\n<p><em>Kaynaklar: BAuA, ECHA, DGUV, AB Komisyonu<\/em><\/p>\n","protected":false},"template":"","carcinogens":[2553],"class_list":["post-57897","fact","type-fact","status-publish","hentry","carcinogens-azodyes-tr"],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v28.0 (Yoast SEO v28.0) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>Azo boyalar\u0131 - STOP carcinogens at work<\/title>\n<meta name=\"description\" content=\"Be aware of what you work with! 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