{"id":57898,"date":"2024-01-04T09:21:22","date_gmt":"2024-01-04T09:21:22","guid":{"rendered":"https:\/\/stopcarcinogensatwork.eu\/fact\/44-metilen-bis-2-kloroanilinie-moca\/"},"modified":"2026-10-22T11:31:46","modified_gmt":"2026-10-22T11:31:46","slug":"44-metilen-bis-2-kloroanilinie-moca","status":"publish","type":"fact","link":"https:\/\/stopcarcinogensatwork.eu\/tr\/fact\/44-metilen-bis-2-kloroanilinie-moca\/","title":{"rendered":"4,4-Metilen-bis (2-kloroanilinie) (MOCA)"},"content":{"rendered":"<blockquote><p>2017 y\u0131l\u0131 tahminlerine g\u00f6re, AB genelinde 2.500 \u00e7al\u0131\u015fan\u0131n MOCA&#8217;ya (metilen-bis-[2-kloroanilin]) potansiyel olarak exposure oldu\u011fu varsay\u0131lm\u0131\u015ft\u0131r. REACH y\u00f6netmeli\u011fi kapsam\u0131nda maddeye ili\u015fkin yetkilendirme duty&#8217;leri de\u011fi\u015fti\u011finden, kullan\u0131mlar\u0131n daha da azald\u0131\u011f\u0131 varsay\u0131labilir (ba\u015fvurular &lt; 100 \u00e7al\u0131\u015fan g\u00f6stermektedir). MOCA exposure&#8217;\u0131 esas olarak maddenin ciltten emilimi yoluyla ger\u00e7ekle\u015fir. Madde, S\u0131n\u0131fland\u0131rma, Etiketleme ve Ambalajlama Y\u00f6netmeli\u011fi&#8217;ne g\u00f6re Carc. 1B (b\u00fcy\u00fck \u00f6l\u00e7\u00fcde hayvan kan\u0131tlar\u0131na dayanarak insanlar i\u00e7in carcinogen potansiyeli oldu\u011fu varsay\u0131lan maddeler) olarak uyumla\u015ft\u0131r\u0131lm\u0131\u015f bir s\u0131n\u0131fland\u0131rmaya sahiptir.    <\/p><\/blockquote>\n<p>Carcinogen&#8217;in insanlarda muhtemel hedefi, mesane kanserine yol a\u00e7an mesane \u00fcrotelidir.<\/p>\n<h2>Risklerin ortaya \u00e7\u0131kt\u0131\u011f\u0131 yerler<\/h2>\n<p>exposure&#8217;\u0131n meydana geldi\u011fi ana sekt\u00f6r, y\u00fcksek performansl\u0131 poli\u00fcretan \u00fcr\u00fcnlerin form\u00fclasyonu ve \u00fcretimidir; \u00f6rne\u011fin, s\u0131cak d\u00f6k\u00fcm poli\u00fcretan \u00fcr\u00fcnler, \u00f6zellikle a\u011f\u0131r hizmet tipi silindirler, gergi pedleri ve yay bloklar\u0131 i\u00e7in y\u00fcksek performansl\u0131 poli\u00fcretanlar ve \u00f6zel yap\u0131m silindirler. Y\u00fcksek MOCA exposure riski ta\u015f\u0131yan g\u00f6revler aras\u0131nda MOCA peletlerinin tart\u0131lmas\u0131, MOCA&#8217;n\u0131n eritilmesi, erimi\u015f MOCA&#8217;n\u0131n da\u011f\u0131t\u0131lmas\u0131 ve erimi\u015f MOCA&#8217;n\u0131n \u00f6n polimerle kar\u0131\u015ft\u0131r\u0131lmas\u0131 yer al\u0131r. Asya-Pasifik b\u00f6lgesinde, \u00e7at\u0131 kaplama ve ah\u015fap s\u0131zd\u0131rmazl\u0131k uygulamalar\u0131nda da bir k\u00fcrleme maddesi olarak kullan\u0131l\u0131r.  <\/p>\n<h2>Madde hakk\u0131nda daha fazla bilgi<\/h2>\n<p>Saf MOCA renksiz kristal bir kat\u0131 madde olmas\u0131na ra\u011fmen, en yayg\u0131n olarak kullan\u0131lan formlar\u0131 (end\u00fcstriyel s\u0131n\u0131f) a\u00e7\u0131k kahverengi renkli peletler veya pullard\u0131r. Hafif bir amin kokusu vard\u0131r, suda \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc \u00e7ok d\u00fc\u015f\u00fckt\u00fcr ve \u0131s\u0131t\u0131ld\u0131\u011f\u0131nda patlayabilir. <\/p>\n<p>AB taraf\u0131ndan 0,01 mg\/m\u00b3 olarak belirlenen ba\u011flay\u0131c\u0131 mesleki exposure s\u0131n\u0131r\u0131 y\u00fcr\u00fcrl\u00fcktedir.<\/p>\n<h2>Olu\u015fabilecek tehlikeler<\/h2>\n<p>MOCA, kullan\u0131m \u015fekli nedeniyle hem deriden hem de solunum yolundan emilir. MOCA\u2019n\u0131n lipofilik yap\u0131s\u0131, nispeten k\u00fc\u00e7\u00fck molek\u00fcl boyutu ve reaktif amin gruplar\u0131n\u0131n varl\u0131\u011f\u0131 nedeniyle deriden emilimi m\u00fcmk\u00fcnd\u00fcr. En y\u00fcksek konsantrasyonlar karaci\u011ferde \u00f6l\u00e7\u00fcl\u00fcr. Emilim g\u00f6steren maddenin \u00e7o\u011fu birka\u00e7 g\u00fcn i\u00e7inde idrar ve d\u0131\u015fk\u0131 yoluyla at\u0131l\u0131r.   <\/p>\n<p>A\u015f\u0131r\u0131 ve ani exposures can cause irritation and a burning sensation on the skin and in the eyes, nausea, and effects on the gastrointestinal and renal systems. The EU also established a \u201cskin note\u201d for MOCA, which indicates that dermal exposure can contribute significantly to the total exposure. <\/p>\n<p>MOCA&#8217;ya uzun s\u00fcre exposure g\u00f6stermek mesane kanserine yol a\u00e7abilir.  <strong>The latency period between the exposure and the MOCA-related bladder cancer occurrence is on average 11.5 years and can extend to 45 years.<\/strong><\/p>\n<h2>Yapabilecekleriniz<\/h2>\n<p>M\u00fcmk\u00fcn oldu\u011fu durumlarda, bu maddenin yerine ba\u015fka bir maddenin kullan\u0131lmas\u0131 d\u00fc\u015f\u00fcn\u00fclmelidir. Alternatifler mevcut de\u011filse veya MOCA yan \u00fcr\u00fcn olarak ortaya \u00e7\u0131kabiliyorsa, ne zaman \u00f6nlem al\u0131nmas\u0131 gerekti\u011finin bilinebilmesi i\u00e7in d\u00fczenli exposure de\u011ferlendirmeleri yap\u0131lmal\u0131d\u0131r. <\/p>\n<p>Poli\u00fcretan \u00fcretiminde MOCA kullan\u0131m\u0131 i\u00e7in s\u0131k\u0131 ko\u015fullar bulunmal\u0131d\u0131r. \u00d6zellikle, tesis genelinde iyi bir genel d\u00fczen de gereklidir ve \u00e7al\u0131\u015fanlar kendi \u00e7al\u0131\u015fma alanlar\u0131n\u0131n sorumlulu\u011funu \u00fcstlenmeli ve zeminleri vb. temizlemelidir. MOCA&#8217;n\u0131n kullan\u0131ld\u0131\u011f\u0131 alanlara eri\u015fim yetkili personel ile s\u0131n\u0131rland\u0131r\u0131lmal\u0131 ve \u00e7al\u0131\u015fanlara hangi KKD&#8217;leri giymeleri gerekti\u011fini hat\u0131rlatmak i\u00e7in g\u00fcvenlik i\u015faretleri yerle\u015ftirilmelidir. MOCA, yaln\u0131zca yetkili personelin eri\u015febilece\u011fi ayr\u0131 depolarda saklanmal\u0131d\u0131r. Yar\u0131 end\u00fcstriyel ve makine d\u00f6k\u00fcm\u00fcnde KKD (ki\u015fisel koruma ekipman\u0131) kullan\u0131m\u0131 zorunlu hale getirilmelidir.    <\/p>\n<p>\u00c7al\u0131\u015fanlar, exposure&#8217;un etkilerinin fark\u0131nda olmal\u0131 ve exposure&#8217;u \u00f6nlemek amac\u0131yla MOCA ile g\u00fcvenli bir \u015fekilde \u00e7al\u0131\u015fmak i\u00e7in gerekli kontrol tedbirleri konusunda d\u00fczenli olarak e\u011fitilmelidir. Ciltte ve g\u00f6zlerde yanma hissi gibi erken belirtileri bildirmeleri i\u00e7in te\u015fvik edilmelidir. Bu nedenle bir i\u015f sa\u011fl\u0131\u011f\u0131 hekiminin s\u00fcrece dahil edilmesi tavsiye edilir.  <\/p>\n<p>Biyomonitoring, \u015fu anda i\u015f ortamlar\u0131nda MOCA&#8217;ya maruz kalma d\u00fczeyini tahmin etmek i\u00e7in en iyi y\u00f6ntemdir. Biyomonitoring uygulan\u0131yorsa, numune al\u0131m\u0131 vardiya sonras\u0131 ve \u00e7al\u0131\u015fma haftas\u0131n\u0131n sonunda yap\u0131lmal\u0131d\u0131r. <\/p>\n<p>Maruz kalma kaynaklar\u0131n\u0131 kontrol alt\u0131na almak i\u00e7in biyomonit\u00f6rleme, hava izleme ve uygun oldu\u011fu durumlarda cilt ve y\u00fczey kirlili\u011fi \u00f6l\u00e7\u00fcmleriyle desteklenmelidir.<\/p>\n<p>\u00c7al\u0131\u015fanlar\u0131n, gerekirse koruyucu giysiler, eldivenler, ayakkab\u0131lar, ba\u015fl\u0131klar, do\u011frudan havaland\u0131rmal\u0131 g\u00f6zl\u00fckler ve solunum maskeleri gibi yeterli ki\u015fisel koruma ekipman\u0131na sahip olmalar\u0131n\u0131 sa\u011flay\u0131n.<\/p>\n<p><em>Kaynaklar: RAC, IARC, ATSDR, AGS, NIOSH, COM<\/em><\/p>\n","protected":false},"template":"","carcinogens":[2558],"class_list":["post-57898","fact","type-fact","status-publish","hentry","carcinogens-44-metilen-bis-2-kloroanilinie-moca"],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v28.8 (Yoast SEO v28.8) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>4,4-Metilen-bis (2-kloroanilinie) (MOCA) - \u0130\u015fyerinde carcinogen maddeleri DURDURUN<\/title>\n<meta name=\"description\" content=\"MOCA&#039;ya exposure esas olarak deri yoluyla ger\u00e7ekle\u015fir. 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